Laboratoire des Interactions Moléculaires et Réactivité Chimique et Photochimique
UMR 5623

Une de nos publications fait la couverture du journal Macromolecular Chemistry and Physics

Simon Harrisson de l'équipe P3R a participé aux travaux de recherche récemment publiés sous le titre :

Phosphorus-Containing Gradient (Block) Copolymers via RAFT Polymerization and Postpolymerization Modification
Macromol. Chem. Phys., 2016, 217, 2310-2320
Sykes, K.J. ; Harrisson, S. ; Keddie, D.J.

RAFT copolymerization of styrene and 4-(diphenylphosphino)styrene is explored to establish the statistical distribution of the phosphine-functional monomer within the copolymer. RAFT copolymerization provides phosphine-functional copolymers of low dispersity. Estimation of reactivity ratios indicates DPPS has a strong tendency to homopolymerize while St preferentially copolymerizes with DPPS. Block copolymers as well as polymeric phosphine oxides and phosphonium salts are also prepared.

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